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- W3019124293 abstract "We report for the first time the synthesis of well-defined bismuth/phosphorus nanoparticles (Bi/P NPs) based on silyl-halide elimination by reaction of BiX3 (X = I, Cl) and P(SiMe3)3 in the presence of different types of stabilizing ligands, such as cinchonidine, 4-(3-phenylpropyl)pyridine, and polyvinylpyrrolidone. This synthetic approach led to spherical, small, and monodisperse NPs [mean diameter ca. 2.0–2.5 nm determined by transmission electron microscopy (TEM)]. Wide-ranging characterization of these NPs, including TEM, powder X-ray diffraction, and small-angle X-ray scattering, and several spectroscopic techniques, such as X-ray fluorescence, IR, and solid-state NMR, proved the formation of a core/shell structure constituted by a crystalline Bi(0) core and amorphous P-containing shells, representing a unique case of phase segregation for metal/phosphorus materials reported in the literature. The assessed reactivity of the as-prepared Bi/P NPs evidenced their potential application in the synthesis of phosphine (PH3) in a safer way than the conventional approach using P4 (white phosphorus) and in a sharp contrast with the reported reactivity of amorphous red phosphorus." @default.
- W3019124293 created "2020-05-01" @default.
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- W3019124293 date "2020-04-23" @default.
- W3019124293 modified "2023-10-16" @default.
- W3019124293 title "Nanoscale Metal Phosphide Phase Segregation to Bi/P Core/Shell Structure. Reactivity as a Source of Elemental Phosphorus" @default.
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- W3019124293 doi "https://doi.org/10.1021/acs.chemmater.0c00478" @default.
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