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- W3019945900 abstract "Abstract Fluorinated aziridines are very important structural motifs, but methods access to such structures are still very rare. In this paper, we report a mild, catalyst‐free and operationally simple strategy for the direct aminofluoroalkylation of olefins driven by the noncovalent interaction between N ‐allylanilines and fluoroalkyl iodides. This photochemical transformation features synthetic simplicity, mild reaction conditions, without the use of any photoredox catalyst, and high functional group tolerance. Moreover, the structures can be used as important precursors for the synthesis of β ‐fluoroalkylated alkylamine derivatives, such as fluorinated amino acids and fluorinated 2‐pyrrolidinones. magnified image" @default.
- W3019945900 created "2020-05-01" @default.
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- W3019945900 date "2020-05-05" @default.
- W3019945900 modified "2023-10-14" @default.
- W3019945900 title "Catalyst‐Free and Visible Light Promoted Aminofluoroalkylation of Unactivated Alkenes: An Access to Fluorinated Aziridines" @default.
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- W3019945900 doi "https://doi.org/10.1002/adsc.202000342" @default.
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