Matches in SemOpenAlex for { <https://semopenalex.org/work/W3020020725> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W3020020725 abstract "Whereas the majority of ions in the bulk of a solvent-free ionic liquid is bound into clusters, this is expected to change in the electrical double layer (EDL), in which the resulting electric field 'prefers' to interact with electrical monopoles-free, unclustered ions. The competition between the propensity of ions to stay in a clustered state and the reduction of the energy of ions in electric field in the free state determines the resulting portion of free ions in the EDL. We present a study of this effect, based on the simplest possible mean-field theory. 'Cracking' of ion clusters into individual ions in electric field is accompanied by the change of the dielectric response of ionic liquid which is different in clustered and unclustered states. The predictions of the theory are verified and further explored by specially performed molecular dynamics simulations. A particular finding of the theory is that the differential capacitance vs potential curve displays a bell shape despite low concentration of free charge carriers, because the dielectric response of bound ions reduces the threshold concentration of the bell- to camel-shape transition. Whereas qualitatively these findings make perfect sense, in reality the exact numbers and criteria might be different as the presented simple theory does not take into account overscreening and oscillating charge and electrostatic potential distributions near the electrode. This is why testing the theory with computer simulations is essential, but the latter basically reproduce the qualitative conclusions of the theory." @default.
- W3020020725 created "2020-05-01" @default.
- W3020020725 creator A5027359414 @default.
- W3020020725 creator A5027376285 @default.
- W3020020725 creator A5033221844 @default.
- W3020020725 creator A5062647351 @default.
- W3020020725 creator A5065482772 @default.
- W3020020725 creator A5084706385 @default.
- W3020020725 creator A5085530250 @default.
- W3020020725 date "2020-04-23" @default.
- W3020020725 modified "2023-09-27" @default.
- W3020020725 title "Enforced freedom: electric-field-induced declustering of ionic-liquid ions in the double layer" @default.
- W3020020725 cites W3100805220 @default.
- W3020020725 hasPublicationYear "2020" @default.
- W3020020725 type Work @default.
- W3020020725 sameAs 3020020725 @default.
- W3020020725 citedByCount "0" @default.
- W3020020725 crossrefType "posted-content" @default.
- W3020020725 hasAuthorship W3020020725A5027359414 @default.
- W3020020725 hasAuthorship W3020020725A5027376285 @default.
- W3020020725 hasAuthorship W3020020725A5033221844 @default.
- W3020020725 hasAuthorship W3020020725A5062647351 @default.
- W3020020725 hasAuthorship W3020020725A5065482772 @default.
- W3020020725 hasAuthorship W3020020725A5084706385 @default.
- W3020020725 hasAuthorship W3020020725A5085530250 @default.
- W3020020725 hasConcept C121332964 @default.
- W3020020725 hasConcept C133386390 @default.
- W3020020725 hasConcept C145148216 @default.
- W3020020725 hasConcept C147597530 @default.
- W3020020725 hasConcept C154881586 @default.
- W3020020725 hasConcept C159467904 @default.
- W3020020725 hasConcept C161790260 @default.
- W3020020725 hasConcept C178790620 @default.
- W3020020725 hasConcept C184779094 @default.
- W3020020725 hasConcept C185592680 @default.
- W3020020725 hasConcept C192562407 @default.
- W3020020725 hasConcept C2182769 @default.
- W3020020725 hasConcept C49040817 @default.
- W3020020725 hasConcept C59593255 @default.
- W3020020725 hasConcept C60799052 @default.
- W3020020725 hasConcept C62520636 @default.
- W3020020725 hasConceptScore W3020020725C121332964 @default.
- W3020020725 hasConceptScore W3020020725C133386390 @default.
- W3020020725 hasConceptScore W3020020725C145148216 @default.
- W3020020725 hasConceptScore W3020020725C147597530 @default.
- W3020020725 hasConceptScore W3020020725C154881586 @default.
- W3020020725 hasConceptScore W3020020725C159467904 @default.
- W3020020725 hasConceptScore W3020020725C161790260 @default.
- W3020020725 hasConceptScore W3020020725C178790620 @default.
- W3020020725 hasConceptScore W3020020725C184779094 @default.
- W3020020725 hasConceptScore W3020020725C185592680 @default.
- W3020020725 hasConceptScore W3020020725C192562407 @default.
- W3020020725 hasConceptScore W3020020725C2182769 @default.
- W3020020725 hasConceptScore W3020020725C49040817 @default.
- W3020020725 hasConceptScore W3020020725C59593255 @default.
- W3020020725 hasConceptScore W3020020725C60799052 @default.
- W3020020725 hasConceptScore W3020020725C62520636 @default.
- W3020020725 hasLocation W30200207251 @default.
- W3020020725 hasOpenAccess W3020020725 @default.
- W3020020725 hasPrimaryLocation W30200207251 @default.
- W3020020725 hasRelatedWork W1534677149 @default.
- W3020020725 hasRelatedWork W1983221144 @default.
- W3020020725 hasRelatedWork W2035074379 @default.
- W3020020725 hasRelatedWork W2101972116 @default.
- W3020020725 hasRelatedWork W2111886909 @default.
- W3020020725 hasRelatedWork W2128765170 @default.
- W3020020725 hasRelatedWork W2166169036 @default.
- W3020020725 hasRelatedWork W2327596206 @default.
- W3020020725 hasRelatedWork W2464327936 @default.
- W3020020725 hasRelatedWork W2561477855 @default.
- W3020020725 hasRelatedWork W2611038134 @default.
- W3020020725 hasRelatedWork W2709089725 @default.
- W3020020725 hasRelatedWork W2889099511 @default.
- W3020020725 hasRelatedWork W2968662963 @default.
- W3020020725 hasRelatedWork W2985241941 @default.
- W3020020725 hasRelatedWork W3024593341 @default.
- W3020020725 hasRelatedWork W3094964479 @default.
- W3020020725 hasRelatedWork W3100855173 @default.
- W3020020725 hasRelatedWork W3176483955 @default.
- W3020020725 hasRelatedWork W2576129578 @default.
- W3020020725 isParatext "false" @default.
- W3020020725 isRetracted "false" @default.
- W3020020725 magId "3020020725" @default.
- W3020020725 workType "article" @default.