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- W3020525526 endingPage "7594" @default.
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- W3020525526 abstract "Nickel-catalyzed decarbonylation of acylsilanes is developed. In sharp contrast to cross-coupling reactions of acylsilanes, in which the silyl group serves as a leaving group, the silyl group is retained in the product in this decarbonylation reaction. Although the strong binding of the dissociated CO to the nickel center frequently hinders catalyst turnover in nickel-mediated decarbonylative reactions, this reaction can be catalyzed by nickel complexes bearing a CO ligand." @default.
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- W3020525526 date "2020-04-28" @default.
- W3020525526 modified "2023-09-29" @default.
- W3020525526 title "Nickel-Catalyzed Decarbonylation of Acylsilanes" @default.
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- W3020525526 doi "https://doi.org/10.1021/acs.joc.0c00772" @default.
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