Matches in SemOpenAlex for { <https://semopenalex.org/work/W3020787585> ?p ?o ?g. }
- W3020787585 endingPage "5461" @default.
- W3020787585 startingPage "5454" @default.
- W3020787585 abstract "The di-tert-alkylphosphino motif is common to many best-in-class ligands for late-transition-metal catalysis. However, the structural diversity of these privileged substructures is currently limited by the need to manipulate highly toxic, highly reactive reagents and intermediates in their synthesis. In response to this longstanding challenge, we report an umpolung strategy for the synthesis of structurally diverse di-tert-alkylphosphine building blocks via SN1 alkylation of in situ generated PH3 gas. We show that the products—which are isolated as air-stable, odorless phosphonium salts—can be used directly in the preparation of key synthetic intermediates and ligand classes. The di-tert-alkylphosphino building blocks that are accessible using our methodology therefore enable facile expansion of extant ligand classes by modification of a previously invariant vector; we demonstrate that these modifications affect the steric and electronic properties of the ligands and can be used to tune their performance in catalysis." @default.
- W3020787585 created "2020-05-01" @default.
- W3020787585 creator A5018772705 @default.
- W3020787585 creator A5023923061 @default.
- W3020787585 creator A5078279657 @default.
- W3020787585 date "2020-04-24" @default.
- W3020787585 modified "2023-10-18" @default.
- W3020787585 title "Expanding Ligand Space: Preparation, Characterization, and Synthetic Applications of Air-Stable, Odorless Di-<i>tert</i>-alkylphosphine Surrogates" @default.
- W3020787585 cites W1840339619 @default.
- W3020787585 cites W1964625267 @default.
- W3020787585 cites W1965277338 @default.
- W3020787585 cites W1969645718 @default.
- W3020787585 cites W1990528343 @default.
- W3020787585 cites W1994493285 @default.
- W3020787585 cites W1996417497 @default.
- W3020787585 cites W1997159316 @default.
- W3020787585 cites W2004867175 @default.
- W3020787585 cites W2006443171 @default.
- W3020787585 cites W2016041703 @default.
- W3020787585 cites W2029492712 @default.
- W3020787585 cites W2033383024 @default.
- W3020787585 cites W2038224611 @default.
- W3020787585 cites W2042540149 @default.
- W3020787585 cites W2044986525 @default.
- W3020787585 cites W2046073176 @default.
- W3020787585 cites W2061591871 @default.
- W3020787585 cites W2063549773 @default.
- W3020787585 cites W2070017880 @default.
- W3020787585 cites W2078310676 @default.
- W3020787585 cites W2084493815 @default.
- W3020787585 cites W2092808790 @default.
- W3020787585 cites W2095903872 @default.
- W3020787585 cites W2137667280 @default.
- W3020787585 cites W2139078293 @default.
- W3020787585 cites W2145273214 @default.
- W3020787585 cites W2153587535 @default.
- W3020787585 cites W2163936405 @default.
- W3020787585 cites W2165352032 @default.
- W3020787585 cites W2279184808 @default.
- W3020787585 cites W2302985703 @default.
- W3020787585 cites W2313623212 @default.
- W3020787585 cites W2313777765 @default.
- W3020787585 cites W2316336126 @default.
- W3020787585 cites W2319930992 @default.
- W3020787585 cites W2323133649 @default.
- W3020787585 cites W2330690482 @default.
- W3020787585 cites W2367339179 @default.
- W3020787585 cites W2395694424 @default.
- W3020787585 cites W2467400748 @default.
- W3020787585 cites W2525864328 @default.
- W3020787585 cites W2560245628 @default.
- W3020787585 cites W2569590428 @default.
- W3020787585 cites W2605784004 @default.
- W3020787585 cites W2753269481 @default.
- W3020787585 cites W2754934466 @default.
- W3020787585 cites W2762195396 @default.
- W3020787585 cites W2768001238 @default.
- W3020787585 cites W2787469589 @default.
- W3020787585 cites W2789928140 @default.
- W3020787585 cites W2790853432 @default.
- W3020787585 cites W2809666431 @default.
- W3020787585 cites W2889946035 @default.
- W3020787585 cites W2891423525 @default.
- W3020787585 cites W2897314507 @default.
- W3020787585 cites W2898716447 @default.
- W3020787585 cites W2901392948 @default.
- W3020787585 cites W2903946529 @default.
- W3020787585 cites W2911476340 @default.
- W3020787585 cites W2913971608 @default.
- W3020787585 cites W2923094332 @default.
- W3020787585 cites W2942728962 @default.
- W3020787585 cites W2944567070 @default.
- W3020787585 cites W2950914212 @default.
- W3020787585 cites W2952392597 @default.
- W3020787585 cites W2952558059 @default.
- W3020787585 cites W2957435651 @default.
- W3020787585 doi "https://doi.org/10.1021/acscatal.0c01414" @default.
- W3020787585 hasPublicationYear "2020" @default.
- W3020787585 type Work @default.
- W3020787585 sameAs 3020787585 @default.
- W3020787585 citedByCount "15" @default.
- W3020787585 countsByYear W30207875852021 @default.
- W3020787585 countsByYear W30207875852022 @default.
- W3020787585 countsByYear W30207875852023 @default.
- W3020787585 crossrefType "journal-article" @default.
- W3020787585 hasAuthorship W3020787585A5018772705 @default.
- W3020787585 hasAuthorship W3020787585A5023923061 @default.
- W3020787585 hasAuthorship W3020787585A5078279657 @default.
- W3020787585 hasBestOaLocation W30207875852 @default.
- W3020787585 hasConcept C116569031 @default.
- W3020787585 hasConcept C161790260 @default.
- W3020787585 hasConcept C164361826 @default.
- W3020787585 hasConcept C170493617 @default.
- W3020787585 hasConcept C178300618 @default.
- W3020787585 hasConcept C178790620 @default.
- W3020787585 hasConcept C178907741 @default.
- W3020787585 hasConcept C185592680 @default.
- W3020787585 hasConcept C201194858 @default.