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- W3021173676 abstract "Semiconductor ionic electrolytes have obtained much attention because of good ionic conductivity and electrochemical performance. Novel semiconductor ionic NSDC (Ce0.8Sm0.2O2-δ-Na2CO3)-LCCN (LiCo0·225Cu0·075Ni0·7O3-δ) composite materials have been adopted as electrolyte membrane for the first time, in which symmetrical cell composed of NSDC-LCCN membrane is constructed with Ni0·8Co0·15Al0·05LiO2 (NCAl)-pasted Ni foam electrodes. An open circuit voltage (OCV) above 1 V and improved power density are obtained in the NSDC-LCCN cells, which confirms the functionality of the proposed semiconductor ionic materials. Meanwhile, X-ray diffractometer (XRD) and Scanning electron microscope (SEM) analyses identify the phase purity and homogenous nanocomposite morphology of all the NSDC-LCCN materials samples with various mass ratios. The performance illustrated by much more steady instead of transient state evaluation reveals that 3NSDC-LCCN composite electrolyte is most optimum, and the corresponding cell exhibits a considerable maximum power density of 598 mW cm−2 at 550 °C, over five times of that of pure NSDC electrolyte cells. Short-term duration test of 3NSDC-LCCN cell at 550 °C shows that the cell could steadily operate up to ~9 h without obvious degradation at a remarkable current density of 469 mA cm−2, which indicates that NSDC-LCCN composite electrolyte is a promising material for low temperature solid oxide fuel cells." @default.
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- W3021173676 date "2020-05-01" @default.
- W3021173676 modified "2023-09-27" @default.
- W3021173676 title "Semiconductor ionic Ce0.8Sm0.2O2-δ-Na2CO3 – LiCo0.225Cu0.075Ni0.7O 3-δ composite material as electrolyte for low temperature solid oxide fuel cells" @default.
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- W3021173676 doi "https://doi.org/10.1016/j.ijhydene.2019.12.092" @default.
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