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• W3021532001 abstract "Abstract Reported here is the asymmetric synthesis of N ‐Boc‐protected (2 S ,3 S )‐3‐amino‐2‐hydroxyoctadecanoic acid, a component of ralstonin A and ralstoamide A. Key synthetic steps include alkylation of chiral Ni(II) complex of glycine Schiff base, conversion of COOH to keto acid (CO−COOH) and reduction of the carbonyl group to generate α ‐hydroxy functionality. The structure and absolute configuration of (2 S ,3 S )‐ N ‐Boc‐3‐amino‐2‐hydroxyoctadecanoic acid was shown to be identical to that of the naturally occurring compound." @default.
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• W3021532001 date "2020-06-05" @default.
• W3021532001 modified "2023-10-18" @default.
• W3021532001 title "Synthesis of Ahod Moiety of Ralstonin A Using Amino Acid <i>Schiff</i> Base Ni(II)‐Complex Chemistry" @default.
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• W3021532001 doi "https://doi.org/10.1002/hlca.202000077" @default.
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