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- W3021547877 abstract "This chapter presents that Metal Dusting (MD) is a high-temperature corrosion process, a disintegration of metals into a dust of fine metal particles and graphite, which occurs in strongly carburizing atmospheres at carbon activities aC >> 1 in the temperature range 400–1000 °C. Metal dusting attacks iron, low- and high-alloy steels, nickel, and cobalt-based alloys. In the case of iron and steels, during metal dusting, cementite (Fe3C) forms as an intermediate phase, which decomposes into graphite and iron, whereas nickel disintegrates by direct inward growth of graphite. The chapter provides an overview of the effect of H2S on metal dusting of iron. It further discusses effect of H2S on carburization kinetics and graphite formation, carbon diffusion in cementite and Hägg carbide (Fe5C2), thermodynamics of Hägg carbide formation, decomposition of Fe3C and Fe5C2, iron sulfide formation in atmospheres containing H2S and practical aspects of sulfur adsorption." @default.
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- W3021547877 date "2007-01-01" @default.
- W3021547877 modified "2023-10-18" @default.
- W3021547877 title "Effect of H 2 S on metal dusting of iron" @default.
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- W3021547877 doi "https://doi.org/10.1533/9781845693350.76" @default.
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