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- W3021556285 abstract "High-pressure Raman studies have been carried out on single crystalline C₆₀(Fc)₂ nanosheets up to 25.4 GPa. Our results show that the charge transfer between Fc (ferrocene) and C₆₀ increases in the low-pressure range. Above 5 GPa, C₆₀ molecules start to form a chainlike polymer structure, and this polymerization is reversible upon decompression, in contrast to that of pristine C₆₀. The special layered structure of C₆₀(Fc)₂ restricts the polymerization of C₆₀ molecules in some directions and explains the formation of the linear chainlike polymeric structure of the C₆₀ lattice under pressure. We suggest that the reversible polymerization is related to the increased charge transfer and the overridden steric repulsion of counterions." @default.
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- W3021556285 date "2012-01-01" @default.
- W3021556285 modified "2023-09-27" @default.
- W3021556285 title "Reversible Polymerization in Doped Fullerides Under Pressure: The Case Of C60(Fe(C5H5)2)2 B" @default.
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