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- W3021714503 abstract "Publisher SummaryThis chapter focuses on the techniques employed to study chemical kinetics. In conventional kinetic methods, in which the reactants are mixed and homogenized by simple addition and shaking, and the progress of the reaction measured by analytical or physical methods; the time of mixing has to be short, relative to that of the reaction. For fast reactions, these experimental conditions are not met, so these methods cannot be used. To overcome this problem, various routes can be followed that include decreasing the rate of the reaction by decreasing the concentration of reagents or the temperature; decreasing the time interval of mixing, using flow methods; rapid perturbation of equilibrium; and observing the competition between the reaction of interest and another fast process whose rate is known. The chapter provides several flow methods to study the chemical reactions. One of the methods is continuous flow method—in this, the reactants are injected continuously into the mixing chamber, leading to a profile of concentration of reactants and products along the detection tube, which does not change with time. Knowing the rate of flow, the reaction time can be related to the distance between the mixing chamber and the place where the reactants or products of the reaction are observed by whatever analytical technique is used." @default.
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- W3021714503 date "2007-01-01" @default.
- W3021714503 modified "2023-10-16" @default.
- W3021714503 title "Experimental Methods" @default.
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- W3021714503 doi "https://doi.org/10.1016/b978-044452186-6/50003-1" @default.
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