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- W3021895983 abstract "Glasses with compositions xFe2O3.(40-x)M.60B2O3 (M= Bi2O3 and PbO) have been prepared using the standard melt-quenching technique. Each sample was characterized by study of XRD and SEM patterns. The structural properties such as glass transition temperature, density, molar volume etc. have been studied of each sample. The glass transition temperature increases which is due to the replacing of B-O-B bonds by more durable B-O-Fe2+ or B-O-Fe3+ bonds with increasing Fe2O3 content whereas the density decreases is due to the replacement of heavier cation (Bi or Pb) by the lighter one (Fe) in both the series. The density of Fe2O3−PbO-B2O3 (FPB) glass samples is lower than that of corresponding Fe2O3-Bi2O3-B2O3 (FBB) suggesting thereby the addition of PbO with Fe2O3 produces more non-bridging oxygens (NBOs) than Bi2O3." @default.
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- W3021895983 date "2020-01-01" @default.
- W3021895983 modified "2023-10-16" @default.
- W3021895983 title "Characterization and structural properties of Fe2O3 based bismuth and lead borate glasses" @default.
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- W3021895983 doi "https://doi.org/10.1063/5.0002453" @default.
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