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• W3021958049 abstract "Abstract Cu 2 MoS 4 is a ternary transition‐metal sulfide that shows great potential in the field of energy conversion and storage, namely catalytic H 2 evolution in water and Li‐, Na‐ or Mg‐ion battery. In this work, we report on a growth mechanism of the single‐crystalline Cu 2 MoS 4 nanotube from (NH 4 ) 2 MoS 4 salt and Cu 2 O nanoparticle. By probing the nature and morphology of solid products generated in function of reaction conditions we find that the crystalline Cu(NH 4 )MoS 4 nanorod is first generated at ambient conditions. The nanorod is then converted into Cu 2 MoS 4 nanotube under hydrothermal treatment due to the Kirkendall effect or a selective etching of the Cu 2 MoS 4 core. Extending the hydrothermal treatment causes a collapse of nanotube generating Cu 2 MoS 4 nanoplate. The catalytic activities of these sulfides are investigated. The Cu 2 MoS 4 shows superior catalytic activity to that of Cu(NH 4 )MoS 4 . Catalytic performance of the former largely depends on its morphology. The nanoplate shows superior catalytic activity to the nanotube, thanks to its higher specific electrochemical surface area." @default.
• W3021958049 created "2020-05-13" @default.
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• W3021958049 date "2020-05-28" @default.
• W3021958049 modified "2023-09-30" @default.
• W3021958049 title "Investigation on the Growth Mechanism of Cu ₂ MoS ₄ Nanotube, Nanoplate and its use as a Catalyst for Hydrogen Evolution in Water" @default.
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• W3021958049 doi "https://doi.org/10.1002/asia.202000344" @default.
• W3021958049 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32374519" @default.
• W3021958049 hasPublicationYear "2020" @default.
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