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- W3022121966 abstract "This chapter focuses on the structure and properties of Shape Memory Polyurethane (SMPU) ionomer. According to the mechanism of shape memory effect, in SMPU, the reversible phase has the melting or glass transition temperature of the soft segments, since the transition temperature is used to hold the temporary deformation. The shape memory effect of PU is mainly influenced by the Hard Segment Content (HSC) and the moiety of its molecular structure. In the center's study, the shape memory effect of SMPU ionomer was studied with cyclic, thermo-mechanical investigation, which was divided into two separate programming processes: cyclic tensile test and strain recovery test. For a segmented PU ionomer, with the introduction of ionic groups on molecular chain, the relations between properties and structure will be of a specific nature. The series of segmented PU ionomers, composed of MDI, PCL, BDO, and DMPA, shows the different properties from the corresponding non-ionomer for the Coulombic force between the ionic groups on the hard segment. The ionomers give higher hardness, modulus, and strength and the effects are more pronounced with increasing HSC and at room temperature. The chapter reviews thermal properties and dynamic mechanical property of SMPU ionomer." @default.
- W3022121966 created "2020-05-13" @default.
- W3022121966 creator A5001811543 @default.
- W3022121966 date "2007-01-01" @default.
- W3022121966 modified "2023-10-16" @default.
- W3022121966 title "Structure and properties of shape memory polyurethane ionomer" @default.
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- W3022121966 doi "https://doi.org/10.1533/9781845693060.113" @default.
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