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- W3022163485 abstract "This chapter discusses the methods for cyclopeptides synthesis. The first synthesis of cyclo-Cys, by reacting the S-Eac precursor with iodine, and a new synthesis of gramicidin S represent some of the noteworthy aspects of cyclopeptide preparation. In a study described in the chapter, a dehydropeptide was cyclized to an imidazole derivative to serve as a model for the biosynthesis of luciferin from a crustacean. Unequivocal evidence for the lichen metabolite cyclo-(R-β-phenyl-β-Ala-Pro)2 was provided by total synthesis. The cyclization step was achieved by ONP peptide-bond formation in pyridine at high dilution. Nine isomeric cyclohexapeptides were synthesized as models for the study of molecular interactions. The cyclic decapeptide antibiotic gramicidin S belongs to a family of similar substances isolated from Bacillus brevis. These antibiotics are not generally used systemically but are valuable, for example, in certain eye-threatening infections." @default.
- W3022163485 created "2020-05-13" @default.
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- W3022163485 date "1975-01-01" @default.
- W3022163485 modified "2023-09-23" @default.
- W3022163485 title "Cyclopeptides" @default.
- W3022163485 doi "https://doi.org/10.1016/b978-0-12-552403-2.50020-0" @default.
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