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- W3022188221 abstract "We synthesized anovd organic radical, 3,4-dichlorophenyl nitronyl nitroxide and characterized magnetic properties in the solid state. An X-ray crystal structure analysis revealed that this molecule formed one-dimensional regular chains in the crystal. Temperature dependence of magnetic susceptibility was reproduced by the antiferromagnetic regular chain model with an exchange interaction J/kB = −8.0 K, which is consistent with the crystal structure. The radical crystal is an example of the regular spin chain in the organic systems that exhibits the largest exchange interaction. Single-crystal cw-ESR exhibited a temperature-dependent shift of g-value. The physical origin of the g-shift is discussed by comparing the observed data with theories describing the short range order effect in antiferromagnetic spin chains. The possibility of demagnetizing field effect on the g-shift in the paramagnetic crystal is also referred" @default.
- W3022188221 created "2020-05-13" @default.
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- W3022188221 date "1964-07-01" @default.
- W3022188221 modified "2023-09-25" @default.
- W3022188221 title "g-value of Fe+++ in II–VI cubic crystals" @default.
- W3022188221 doi "https://doi.org/10.1016/0038-1098(64)90303-5" @default.
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