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- W3022194512 abstract "The formation mechanisms of γ-ray-induced carboxyl (HOCO) and methyl radicals in CO₂ + methane mixed gas hydrates, which are inclusion compounds of H₂O, CO₂, and methane, were investigated. The HOCO and methyl radicals were observed in CO₂ + methane mixed gas hydrates by electron spin resonance (ESR) at 120 K after irradiation at 77 K. The amounts of the HOCO and methyl radicals induced in the mixed hydrates are much higher than those in pure CO₂ and methane hydrates. Both radicals are synergistically formed in the mixed hydrates by efficient reactions between the guest molecules (CO₂ and methane) and the active species (electron, proton, and hydroxyl radical) induced from H₂O." @default.
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- W3022194512 date "2014-01-01" @default.
- W3022194512 modified "2023-09-23" @default.
- W3022194512 title "Synergistic Formation of Carboxyl and Methyl Radicals in CO2 + Methane Mixed Gas Hydrates B" @default.
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