FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3022359339> ?p ?o ?g. }

• W3022359339 endingPage "388" @default.
• W3022359339 startingPage "253" @default.
• W3022359339 abstract "We present an overview of recent experiments performed on water in the deeply supercooled region, a temperature region of fundamental importance in the science of water. We examine data generated by nuclear magnetic resonance, quasi-elastic neutron scattering, Fourier-transform infrared spectroscopy, and Raman spectroscopy, and study water confined in nanometer-scale environments. When contained within small pores, water does not crystallize and can be supercooled well below its homogeneous nucleation temperature Th. On this basis, it is possible to carry out a careful analysis of the well-known thermodynamic anomalies of water. Studying the temperature and pressure dependencies of water dynamics, we show that the liquid-liquid phase transition (LLPT) hypothesis represents a reliable model for describing liquid water. In this model, liquid water is a mixture of two different local structures: a low density liquid (LDL) and a high-density liquid (HDL). The LLPT line terminates at a low-T liquid-liquid critical point. We discuss the following experimental findings: i) the crossover from non-Arrhenius behavior at high T to Arrhenius behavior at low T in transport parameters; ii) the breakdown of the Stokes-Einstein relation; iii) the existence of a Widom line, which is the locus of points corresponding to a maximum correlation length in the P-T phase diagram and which ends in the liquid-liquid critical point; iv) the direct observation of the LDL phase; and v) the minimum in the density at approximately 70K below the temperature of the density maximum. In our opinion these results strongly support the LLPT hypothesis. All of the basic science and technology community should be impressed by the fact that, although the few ideas (apparently elementary) developed concerning water approximately 27 centuries ago have changed very little up to now, because of the current expansion in our knowledge in this area, they can begin to change in the near future." @default.
• W3022359339 created "2020-05-13" @default.
• W3022359339 creator A5003062842 @default.
• W3022359339 creator A5017537902 @default.
• W3022359339 creator A5056648439 @default.
• W3022359339 creator A5057056360 @default.
• W3022359339 creator A5063955327 @default.
• W3022359339 creator A5088514677 @default.
• W3022359339 date "2011-05-01" @default.
• W3022359339 modified "2023-09-26" @default.
• W3022359339 title "Transport properties of supercooled confined water" @default.
• W3022359339 cites W102746271 @default.
• W3022359339 cites W1489910389 @default.
• W3022359339 cites W1492647257 @default.
• W3022359339 cites W1496126658 @default.
• W3022359339 cites W1498356781 @default.
• W3022359339 cites W1511593040 @default.
• W3022359339 cites W1527964677 @default.
• W3022359339 cites W1528929242 @default.
• W3022359339 cites W1537479324 @default.
• W3022359339 cites W1552549684 @default.
• W3022359339 cites W1555502983 @default.
• W3022359339 cites W1573051457 @default.
• W3022359339 cites W1573294821 @default.
• W3022359339 cites W1608120968 @default.
• W3022359339 cites W1636236690 @default.
• W3022359339 cites W1645714275 @default.
• W3022359339 cites W1670616024 @default.
• W3022359339 cites W175132511 @default.
• W3022359339 cites W177408800 @default.
• W3022359339 cites W183550409 @default.
• W3022359339 cites W1850221914 @default.
• W3022359339 cites W1855844464 @default.
• W3022359339 cites W1860287188 @default.
• W3022359339 cites W1964336579 @default.
• W3022359339 cites W1964496713 @default.
• W3022359339 cites W1964534713 @default.
• W3022359339 cites W1964539872 @default.
• W3022359339 cites W1964852724 @default.
• W3022359339 cites W1964908760 @default.
• W3022359339 cites W1965509826 @default.
• W3022359339 cites W1965987863 @default.
• W3022359339 cites W1966056310 @default.
• W3022359339 cites W1966789116 @default.
• W3022359339 cites W1967959168 @default.
• W3022359339 cites W1969824173 @default.
• W3022359339 cites W1969858062 @default.
• W3022359339 cites W1969876897 @default.
• W3022359339 cites W1970404689 @default.
• W3022359339 cites W1971445169 @default.
• W3022359339 cites W1972671100 @default.
• W3022359339 cites W1973321592 @default.
• W3022359339 cites W1974195642 @default.
• W3022359339 cites W1974580048 @default.
• W3022359339 cites W1975181677 @default.
• W3022359339 cites W1976017714 @default.
• W3022359339 cites W1976062239 @default.
• W3022359339 cites W1976499671 @default.
• W3022359339 cites W1976794080 @default.
• W3022359339 cites W1977031640 @default.
• W3022359339 cites W1978502583 @default.
• W3022359339 cites W1981438109 @default.
• W3022359339 cites W1982566701 @default.
• W3022359339 cites W1982817490 @default.
• W3022359339 cites W1983423708 @default.
• W3022359339 cites W1983474142 @default.
• W3022359339 cites W1983718136 @default.
• W3022359339 cites W1983831371 @default.
• W3022359339 cites W1983880717 @default.
• W3022359339 cites W1984123249 @default.
• W3022359339 cites W1985310149 @default.
• W3022359339 cites W1985384647 @default.
• W3022359339 cites W1986804302 @default.
• W3022359339 cites W1987653347 @default.
• W3022359339 cites W1987815728 @default.
• W3022359339 cites W1988121947 @default.
• W3022359339 cites W1990964279 @default.
• W3022359339 cites W1990989967 @default.
• W3022359339 cites W1991049772 @default.
• W3022359339 cites W1991223591 @default.
• W3022359339 cites W1991498626 @default.
• W3022359339 cites W1991667245 @default.
• W3022359339 cites W1991787509 @default.
• W3022359339 cites W1993033824 @default.
• W3022359339 cites W1993273178 @default.
• W3022359339 cites W1993793304 @default.
• W3022359339 cites W1994011618 @default.
• W3022359339 cites W1994515864 @default.
• W3022359339 cites W1995541511 @default.
• W3022359339 cites W1995832393 @default.
• W3022359339 cites W1997647176 @default.
• W3022359339 cites W1997676547 @default.
• W3022359339 cites W1997881715 @default.
• W3022359339 cites W1998391450 @default.
• W3022359339 cites W1998683316 @default.
• W3022359339 cites W1999368175 @default.
• W3022359339 cites W1999679917 @default.
• W3022359339 cites W2000208308 @default.

• next