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• W3022383985 startingPage "121331" @default.
• W3022383985 abstract "The bis(pyridylimino)isoindoline (BPI) ligand is a tridentate chelate that binds to metals via a meridional coordination mode. However, when this ligand forms a complex with Re(CO)3, an almost exclusively facial moiety, the BPI ligand deforms to coordinate in a facial mode. We have in-vestigated this deformation via structural and theoretical means, and the non-planar binding mode of the ligand bathochromically shifts the metal to ligand charge transfer (MLCT) transition." @default.
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• W3022383985 date "2020-07-01" @default.
• W3022383985 modified "2023-09-27" @default.
• W3022383985 title "Binding a meridional ligand in a facial geometry: A square peg in a round hole" @default.
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• W3022383985 doi "https://doi.org/10.1016/j.jorganchem.2020.121331" @default.
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