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• W3022725963 abstract "A photocatalytic system for the dearomative hydroarylation of benzene derivatives has been developed. Using a combination of an organic photoredox catalyst and an amine reductant, this process operates through a reductive radical-polar crossover mechanism where aryl halide reduction triggers a regioselective radical cyclization event, followed by anion formation and quenching to produce a range of complex spirocyclic cyclohexadienes. This light-driven protocol functions at room temperature in a green solvent system (aq. MeCN) without the need for precious metal-based catalysts or reagents or the generation of stoichiometric metal byproducts." @default.
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• W3022725963 date "2020-05-07" @default.
• W3022725963 modified "2023-10-06" @default.
• W3022725963 title "Hydroarylation of Arenes via Reductive Radical-Polar Crossover" @default.
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• W3022725963 doi "https://doi.org/10.1021/jacs.0c03926" @default.
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