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• W3022743301 startingPage "4190" @default.
• W3022743301 abstract "Tetrasubstituted carbon containing two different halogen substituents was constructed in a single-step operation by utilizing the carbene-like reactivity of dioxaphospholene through the tandem reaction of electrophilic and nucleophilic halogenating reagents. It was crucial to devise non-dealkylatable phosphoramidite, which enabled the efficient formation of geminal chlorofluorides from various 1,2-diketones with (PhSO2)2NF and n-Bu4NCl. In addition, selective functionalization of the chlorine substituent was demonstrated, and the absence of halogen scrambling was confirmed." @default.
• W3022743301 created "2020-05-13" @default.
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• W3022743301 date "2020-05-08" @default.
• W3022743301 modified "2023-10-14" @default.
• W3022743301 title "Phosphorus(III)-Mediated, Tandem Deoxygenative Geminal Chlorofluorination of 1,2-Diketones" @default.
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• W3022743301 doi "https://doi.org/10.1021/acs.orglett.0c01258" @default.
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