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- W3022794522 abstract "The 3p Rydberg states of acetone and photodissociation of the acetone cation were studied using time-of-flight(TOF)mass spectrometry.The 3p Rydberg state spectroscopy of acetone was investigated with linearly polarized two-photon resonance enhanced multiphoton ionization(REMPI)from 320 to 337 nm.Several new transition bands were observed in the spectra.In addition to the CH3COCH3 + ion,CH3CO + and CH3 + fragments were observed.The laser power dependences suggest that the CH3COCH3 +,CH3CO + and CH3 + ions are produced in three-,four-,and four-photon processes,respectively.Production of CH3CO + and CH3 + involves excitation of the ground state acetone cation by an additional photon and subsequent decomposition of the excited acetone ion.The average translational energies of CH3CO + and CH3 + from dissociation in CH3COCH3 +(X)+hv→CH3CO + +CH3 and CH3COCH3 +(X)+hv→CH3 + +CH3CO,respectively,were derived from the ion TOF peak profiles." @default.
- W3022794522 created "2020-05-13" @default.
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- W3022794522 date "2010-01-01" @default.
- W3022794522 modified "2023-09-23" @default.
- W3022794522 title "A multiphoton ionization study of acetone using time-of-flight mass spectrometry" @default.
- W3022794522 hasPublicationYear "2010" @default.
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