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• W3022794631 abstract "Chiral salen manganese and copper complexes immobilised on mesoporous silica supports (silica, MCM-41) have been investigated as catalysts in the sulfide to sulfoxide oxidation; the supported catalysts are highly suited to reactions leading to high yields and high sulfoxide/sulfone selectivity while moderate asymmetric induction (up to 30%) was observed. The presence of stable manganyl [Mn(V)O] complexes into support channels have been established, being responsible for catalytic activity. The recovery and reusability of heterogenised Mn- and Cu-catalysts have been studied." @default.
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• W3022794631 date "2004-11-01" @default.
• W3022794631 modified "2023-10-09" @default.
• W3022794631 title "Mesoporous MCM41-heterogenised (salen)Mn and Cu complexes as effective catalysts for oxidation of sulfides to sulfoxides" @default.
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• W3022794631 doi "https://doi.org/10.1016/j.molcata.2004.07.010" @default.
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