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• W3022815854 abstract "The primary goal for selecting reagents is to obtain the desired product in high yield with minimal effort during workup. The suitability of reagents for scale-up work is determined by reactivity/selectivity, cost, availability, ease of scale-up operations, and many other practical considerations. This chapter discusses characteristics of the ideal reagent, safety and toxicity considerations, the importance of examining the cost of reagents, and atom efficiency and presents examples from families of reagents useful for scale-up. The ideal reagent produces the desired product in high yield in the expected time frame with minimal effort needed for workup and isolation of the product. Cost, availability, ease of handling, waste disposal considerations, and other factors become increasingly important as more material is required. Some examples of families of reagents commonly used on scale are shown. Catalytic reagents can sharply decrease costs of both reagents and waste disposal and can increase overall productivity. Catalytic hydrogenation has been a mainstay of the chemical industries for many years. While enzymes have been used commercially for many years, resurgence in using enzymes to prepare optically active materials is underway. This is due to the increasing interest in preparing chiral drugs. The greatest growth area for those companies developing enzymes is in the pharmaceutical market." @default.
• W3022815854 created "2020-05-13" @default.
• W3022815854 creator A5014999580 @default.
• W3022815854 date "2000-01-01" @default.
• W3022815854 modified "2023-09-25" @default.
• W3022815854 title "Reagent Selection" @default.
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• W3022815854 doi "https://doi.org/10.1016/b978-012059475-7/50006-5" @default.
• W3022815854 hasPublicationYear "2000" @default.
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