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• W3022909461 abstract "Germanium nitride (Ge3N4) was examined as a potential negative electrode material for Li-ion batteries. The electrochemistry of Ge3N4 versus Li showed high reversible capacity (500mAh/g) and good capacity retention during cycling. A combination of ex-situ and in-situ x-ray diffraction (XRD), ex-situ transmission electron microscopy (TEM) and ex-situ selective area electron diffraction (SAED) analyses revealed evidence supporting the conversion of a layer of Ge3N4 crystal into an amorphous Li3N+LixGe nanocomposite during the first lithiation. The nanocomposite was electrochemically active via a reversible Li-Ge alloying reaction while a core of unreacted Ge3N4 crystal remained inactive. The lithium/metal nitride conversion reaction process was kinetically hindered resulting in limited capacity. Mechanical milling was found to improve the material capacity." @default.
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• W3022909461 date "2003-07-29" @default.
• W3022909461 modified "2023-10-14" @default.
• W3022909461 title "The electrochemistry of Germanium nitride versus lithium" @default.
• W3022909461 hasPublicationYear "2003" @default.
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