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• W3023134314 abstract "Ion exchange is poorly understood but important chemical reaction in soils, sediments, and aquifers; a process that has profound effects on the solution concentration of many ions. The ion exchange isotherm that describes the relation between solution composition and the ion exchange complex is influenced by two major factors: electrolyte concentration and ion selectivity.Electrolyte concentration affects the exchange isotherm only for asymmetric exchange reactions, the effect being proportional to the ion-charge concentration. Ion selectivity influences symmetric and asymmetric exchange reactions and arises from Coulomb interactions between the ion and the exchange site.The strength of the Coulomb interaction between ion and site is controlled by ion hydration; the hydration shell determines how closely each ion can approach the exchange site. Weakly hydrated ions that are able to shed their hydration shell can bind more strongly to the exchange site than strongly hydrated ions. As a general rule, single-adjustable-parameter exchange isotherms provide an excellent fit of the experimental exchange isotherm. In certain cases (cf. Appendix 4.F) the selectivity coefficient adopts two limiting values representing preferred interlayer hydration states and undergoes an abrupt transition between the two limiting values when the exchange complex reaches a critical value." @default.
• W3023134314 created "2020-05-13" @default.
• W3023134314 creator A5058433757 @default.
• W3023134314 date "2017-01-01" @default.
• W3023134314 modified "2023-10-17" @default.
• W3023134314 title "Ion Exchange" @default.
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• W3023134314 doi "https://doi.org/10.1016/b978-0-12-804178-9.00004-5" @default.
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