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- W3023228746 abstract "The structure and magnetic properties are studied in co-doped Cs2-x K x CuBr4-x Cl x and pressurized Cs2CuBr4 samples. No structural phase transition is found with doping concentration x ⩽ 0.1 and pre-compression pressure up to 4.5 GPa. The maximum susceptibility temperature T max of the zero-field-cooling (ZFC) susceptibility curves decreases slightly with increasing doping concentration and pre-compression pressure, indicating only small changes in the exchange coupling constants. However, an unusual enhancement of the magnetic moment deduced from the ZFC susceptibility is observed in both series samples. A maximum increase of 40% is obtained in Cs1.9K0.1CuBr3.9Cl0.1 sample. The magnetic moment increases almost linearly with decreasing Δ, i.e., defined as the wavenumber difference between the short- and long-bond stretching modes of the CuBr42- tetrahedra in the Raman spectra. The effect is likely due to the recovery of the Cu-3d orbital magnetic moments by strain-induced suppression of Jahn-Teller distortion in CuBr42- tetrahedra." @default.
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- W3023228746 date "2020-04-30" @default.
- W3023228746 modified "2023-09-28" @default.
- W3023228746 title "Strain-induced magnetic moment enhancement in frustrated antiferromagnet Cs<sub>2</sub>CuBr<sub>4</sub>" @default.
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- W3023228746 doi "https://doi.org/10.1088/1361-648x/ab8ecb" @default.
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