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- W3023343205 abstract "Using dissipative particle dynamics simulations,a phase diagram in terms of temperature and lateral chain length was established,related structural parameters and the effective volume fraction of lateral chains f L related to each mesophase were calculated.The experimentally observed pentagonal,hexagonal columnar phase and the lamellar phase where rods are stacked with in-plane order are firstly reproduced. The results show that the phase sequence and structures in the diagram of T-shaped ternary amphiphilies with long rod-like mesogens agree well with previous reports,the effective volume fraction of lateral chains f L related to each mesophase is also quantitatively consistent with the experimental value. These combined results demonstrate that the coarse graining model in our simulation reflects essential structural features of T-shaped real mo-lecules like molecular topology,excluded volume effects,tendency to phase separation,the length-to-width ratio of rod liquid crystal unit and the spatial effects of lateral chains,and they also confirm the fact that the size of lateral chains plays an important role in affecting the self-assembled structures of nonlinear systems and the distribution of each constituent." @default.
- W3023343205 created "2020-05-13" @default.
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- W3023343205 date "2014-01-01" @default.
- W3023343205 modified "2023-09-28" @default.
- W3023343205 title "Dissipative Particle Dynamics Simulation of the Phase Behavior of T-shaped Ternary Amphiphiles Possessing Long Rod-like Mesogens" @default.
- W3023343205 hasPublicationYear "2014" @default.
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