Matches in SemOpenAlex for { <https://semopenalex.org/work/W3023448912> ?p ?o ?g. }
- W3023448912 endingPage "283" @default.
- W3023448912 startingPage "245" @default.
- W3023448912 abstract "This chapter explains optical rotation. THE potential value of optical rotation as a method of investigating polypeptide structure has been fully appreciated only within the last few years. During this time, extensive experimental work on a wide variety of proteins and synthetic polypeptides has revealed striking correlations between their optical rotatory properties and their chain configuration. However, undoubtedly the greatest advance has been in the development of theories of the rotatory properties of helices which have attempted to provide a quantitative basis for the observed configurational effects. The theory has not yet reached a stage where optical rotatory properties can be interpreted absolutely and unambiguously in terms of polypeptide structure and, therefore, the greatest care should be exercised in drawing conclusions from experimental data. The theory is based upon a quantum mechanical consideration of the optical rotation due to a system of spatially equivalent residues forming a regular helix. Every electronic transition due to the dissymmetry of the individual residues is spread into an “exciton” band by interactions between the neighboring residues composing the helix. Within each exciton band, only two transitions due to the helix are “allowed” and can contribute to the optical rotation." @default.
- W3023448912 created "2020-05-13" @default.
- W3023448912 creator A5078713309 @default.
- W3023448912 date "1960-01-01" @default.
- W3023448912 modified "2023-09-25" @default.
- W3023448912 title "OPTICAL ROTATION" @default.
- W3023448912 cites W1585438000 @default.
- W3023448912 cites W170665370 @default.
- W3023448912 cites W1968469989 @default.
- W3023448912 cites W1969067099 @default.
- W3023448912 cites W1972943838 @default.
- W3023448912 cites W1985572111 @default.
- W3023448912 cites W1986227700 @default.
- W3023448912 cites W1989109150 @default.
- W3023448912 cites W1990385782 @default.
- W3023448912 cites W1992833831 @default.
- W3023448912 cites W1994306866 @default.
- W3023448912 cites W2000596904 @default.
- W3023448912 cites W2000784489 @default.
- W3023448912 cites W2002066701 @default.
- W3023448912 cites W2002140726 @default.
- W3023448912 cites W2004540883 @default.
- W3023448912 cites W2005223011 @default.
- W3023448912 cites W2006099339 @default.
- W3023448912 cites W2008419764 @default.
- W3023448912 cites W2008516590 @default.
- W3023448912 cites W2009185452 @default.
- W3023448912 cites W2009578701 @default.
- W3023448912 cites W2012417568 @default.
- W3023448912 cites W2012863389 @default.
- W3023448912 cites W2021270846 @default.
- W3023448912 cites W2022722973 @default.
- W3023448912 cites W2022948039 @default.
- W3023448912 cites W2023957325 @default.
- W3023448912 cites W2027816595 @default.
- W3023448912 cites W2031975112 @default.
- W3023448912 cites W2035066110 @default.
- W3023448912 cites W2043647722 @default.
- W3023448912 cites W2045126200 @default.
- W3023448912 cites W2046531643 @default.
- W3023448912 cites W2046598646 @default.
- W3023448912 cites W2048313566 @default.
- W3023448912 cites W2048871226 @default.
- W3023448912 cites W2049620113 @default.
- W3023448912 cites W2049763180 @default.
- W3023448912 cites W2053415508 @default.
- W3023448912 cites W2056506219 @default.
- W3023448912 cites W2056921448 @default.
- W3023448912 cites W2059471228 @default.
- W3023448912 cites W2059865140 @default.
- W3023448912 cites W2062207917 @default.
- W3023448912 cites W2063182216 @default.
- W3023448912 cites W2065143164 @default.
- W3023448912 cites W2065185654 @default.
- W3023448912 cites W2066417129 @default.
- W3023448912 cites W2066676478 @default.
- W3023448912 cites W2067431091 @default.
- W3023448912 cites W2067477275 @default.
- W3023448912 cites W2070817777 @default.
- W3023448912 cites W2073603992 @default.
- W3023448912 cites W2074698160 @default.
- W3023448912 cites W2075404029 @default.
- W3023448912 cites W2077895914 @default.
- W3023448912 cites W2079218746 @default.
- W3023448912 cites W2079785454 @default.
- W3023448912 cites W2080941246 @default.
- W3023448912 cites W2081907512 @default.
- W3023448912 cites W2082022206 @default.
- W3023448912 cites W2082522136 @default.
- W3023448912 cites W2082808196 @default.
- W3023448912 cites W2083219962 @default.
- W3023448912 cites W2083278200 @default.
- W3023448912 cites W2083484291 @default.
- W3023448912 cites W2086398304 @default.
- W3023448912 cites W2090612075 @default.
- W3023448912 cites W2092598726 @default.
- W3023448912 cites W2092984404 @default.
- W3023448912 cites W2095472970 @default.
- W3023448912 cites W2096152854 @default.
- W3023448912 cites W2105061763 @default.
- W3023448912 cites W2127813765 @default.
- W3023448912 cites W2132241910 @default.
- W3023448912 cites W2134664890 @default.
- W3023448912 cites W2140570804 @default.
- W3023448912 cites W2313568149 @default.
- W3023448912 cites W2315539160 @default.
- W3023448912 cites W2317091548 @default.
- W3023448912 cites W2317281566 @default.
- W3023448912 cites W2317329455 @default.
- W3023448912 cites W2317675313 @default.
- W3023448912 cites W2319360322 @default.
- W3023448912 cites W2321983476 @default.
- W3023448912 cites W2322287009 @default.
- W3023448912 cites W2323563884 @default.
- W3023448912 cites W2324085208 @default.
- W3023448912 cites W2324141240 @default.
- W3023448912 cites W2324191959 @default.
- W3023448912 cites W2324225674 @default.