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• W3023490860 abstract "Computational modeling and accurate simulations of localized surface plasmon resonance (LSPR) absorption properties are reported for gold nanobipyramids (GNBs), a class of metal nanoparticle that features highly tunable, geometry-dependent optical properties. GNB bicone models with spherical tips performed best in reproducing experimental LSPR spectra while the comparison with other geometrical models provided a fundamental understanding of base shapes and tip effects on the optical properties of GNBs. Our results demonstrated the importance of averaging all geometrical parameters determined from transmission electron microscopy images to build representative models of GNBs. By assessing the performances of LSPR absorption spectra simulations based on a quasi-static approximation, we provided an applicability range of this approach as a function of the nanoparticle size, paving the way to the theoretical study of the coupling between molecular electron densities and metal nanoparticles in GNB-based nanohybrid systems, with potential applications in the design of nanomaterials for bioimaging, optics and photocatalysis." @default.
• W3023490860 created "2020-05-13" @default.
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• W3023490860 date "2020-05-07" @default.
• W3023490860 modified "2023-10-17" @default.
• W3023490860 title "Simulating Plasmon Resonances of Gold Nanoparticles with Bipyramidal Shapes by Boundary Element Methods" @default.
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• W3023490860 doi "https://doi.org/10.1021/acs.jctc.0c00269" @default.
• W3023490860 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7584360" @default.
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