Matches in SemOpenAlex for { <https://semopenalex.org/work/W3023578262> ?p ?o ?g. }
- W3023578262 endingPage "10445" @default.
- W3023578262 startingPage "10438" @default.
- W3023578262 abstract "An unsaturated polymer’s cis/trans-olefin content has a significant influence on its properties. For polymers obtained by ring-opening metathesis polymerization (ROMP), the cis/trans-olefin content can be tuned by using specific catalysts. However, cis-selective ROMP has suffered from narrow monomer scope and lack of control over the polymerization (giving polymers with broad molecular weight distributions and prohibiting the synthesis of block copolymers). Herein, we report the versatile cis-selective controlled living ROMP of various endo-tricyclo[4.2.2.02,5]deca-3,9-diene and various norbornene derivatives using a fast-initiating dithiolate-chelated Ru catalyst. Polymers with cis-olefin content as high as 99% could be obtained with high molecular weight (up to Mn of 105.1 kDa) and narrow dispersity (<1.4). The living nature of the polymerization was also exploited to prepare block copolymers with high cis-olefin content for the first time. Furthermore, owing to the successful control over the stereochemistry and narrow dispersity, we could compare cis- and trans-rich polynorbornene and found the former to have enhanced resistance to shear degradation." @default.
- W3023578262 created "2020-05-13" @default.
- W3023578262 creator A5036081066 @default.
- W3023578262 creator A5050806675 @default.
- W3023578262 creator A5059266515 @default.
- W3023578262 creator A5078597191 @default.
- W3023578262 creator A5085830139 @default.
- W3023578262 creator A5085858527 @default.
- W3023578262 date "2020-05-11" @default.
- W3023578262 modified "2023-10-18" @default.
- W3023578262 title "Ru-Catalyzed, <i>cis</i>-Selective Living Ring-Opening Metathesis Polymerization of Various Monomers, Including a Dendronized Macromonomer, and Implications to Enhanced Shear Stability" @default.
- W3023578262 cites W1981015831 @default.
- W3023578262 cites W1986367750 @default.
- W3023578262 cites W1995145268 @default.
- W3023578262 cites W2002470507 @default.
- W3023578262 cites W2005546983 @default.
- W3023578262 cites W2006380085 @default.
- W3023578262 cites W2007252698 @default.
- W3023578262 cites W2012413106 @default.
- W3023578262 cites W2013812539 @default.
- W3023578262 cites W2025407543 @default.
- W3023578262 cites W2030163283 @default.
- W3023578262 cites W2038617846 @default.
- W3023578262 cites W2039217593 @default.
- W3023578262 cites W2043363828 @default.
- W3023578262 cites W2066037930 @default.
- W3023578262 cites W2068580249 @default.
- W3023578262 cites W2071021708 @default.
- W3023578262 cites W2071692667 @default.
- W3023578262 cites W2081405235 @default.
- W3023578262 cites W2106574596 @default.
- W3023578262 cites W2155340863 @default.
- W3023578262 cites W2158307737 @default.
- W3023578262 cites W2228972629 @default.
- W3023578262 cites W2320916039 @default.
- W3023578262 cites W2332307577 @default.
- W3023578262 cites W2333298986 @default.
- W3023578262 cites W2517770397 @default.
- W3023578262 cites W2599228156 @default.
- W3023578262 cites W2685416739 @default.
- W3023578262 cites W2765703624 @default.
- W3023578262 cites W2807576808 @default.
- W3023578262 cites W2809561053 @default.
- W3023578262 cites W2886083702 @default.
- W3023578262 cites W2900968913 @default.
- W3023578262 cites W2913584997 @default.
- W3023578262 cites W2914124033 @default.
- W3023578262 cites W2949744366 @default.
- W3023578262 cites W2963151166 @default.
- W3023578262 cites W2969751250 @default.
- W3023578262 cites W2998128657 @default.
- W3023578262 cites W2999981402 @default.
- W3023578262 cites W3008330842 @default.
- W3023578262 cites W2735087689 @default.
- W3023578262 doi "https://doi.org/10.1021/jacs.0c02785" @default.
- W3023578262 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32392047" @default.
- W3023578262 hasPublicationYear "2020" @default.
- W3023578262 type Work @default.
- W3023578262 sameAs 3023578262 @default.
- W3023578262 citedByCount "27" @default.
- W3023578262 countsByYear W30235782622020 @default.
- W3023578262 countsByYear W30235782622021 @default.
- W3023578262 countsByYear W30235782622022 @default.
- W3023578262 countsByYear W30235782622023 @default.
- W3023578262 crossrefType "journal-article" @default.
- W3023578262 hasAuthorship W3023578262A5036081066 @default.
- W3023578262 hasAuthorship W3023578262A5050806675 @default.
- W3023578262 hasAuthorship W3023578262A5059266515 @default.
- W3023578262 hasAuthorship W3023578262A5078597191 @default.
- W3023578262 hasAuthorship W3023578262A5085830139 @default.
- W3023578262 hasAuthorship W3023578262A5085858527 @default.
- W3023578262 hasConcept C111998727 @default.
- W3023578262 hasConcept C11432220 @default.
- W3023578262 hasConcept C136520611 @default.
- W3023578262 hasConcept C153914509 @default.
- W3023578262 hasConcept C15920480 @default.
- W3023578262 hasConcept C166940927 @default.
- W3023578262 hasConcept C174499055 @default.
- W3023578262 hasConcept C178790620 @default.
- W3023578262 hasConcept C185592680 @default.
- W3023578262 hasConcept C188027245 @default.
- W3023578262 hasConcept C196503311 @default.
- W3023578262 hasConcept C2780227895 @default.
- W3023578262 hasConcept C2780547246 @default.
- W3023578262 hasConcept C44228677 @default.
- W3023578262 hasConcept C48396125 @default.
- W3023578262 hasConcept C521977710 @default.
- W3023578262 hasConceptScore W3023578262C111998727 @default.
- W3023578262 hasConceptScore W3023578262C11432220 @default.
- W3023578262 hasConceptScore W3023578262C136520611 @default.
- W3023578262 hasConceptScore W3023578262C153914509 @default.
- W3023578262 hasConceptScore W3023578262C15920480 @default.
- W3023578262 hasConceptScore W3023578262C166940927 @default.
- W3023578262 hasConceptScore W3023578262C174499055 @default.
- W3023578262 hasConceptScore W3023578262C178790620 @default.
- W3023578262 hasConceptScore W3023578262C185592680 @default.
- W3023578262 hasConceptScore W3023578262C188027245 @default.
- W3023578262 hasConceptScore W3023578262C196503311 @default.