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• W3024256522 abstract "Herein, the phases, defect formation energies, and electrical properties of nominal Sn‐doped LaNb 1– x Sn x O 4–0.5 x and A‐site deficient La 1– x NbO 4–1.5 x materials are reported. LaNb 1– x Sn x O 4–0.5 x shows a solid‐solution limit close to x = 0.03 with the defect formation energy of ≈4.13 eV. Higher conductivities are observed under wet than dry conditions, suggesting a considerable protonic contribution in the Sn‐doped materials. The calculated defect formation energy of ≈9.18 eV for creating La vacancies in La sublattice in LaNbO 4 agrees well with the fact that there are mixed dominating parent LaNbO 4 and minor orthorhombic La 0.33 NbO 3 phases in nominal La 1– x NbO 4–1.5 x samples. The electrical property studies reveal no proton conduction but strong n‐type electronic conduction in La 1– x NbO 4–1.5 x from the minor La 0.33 NbO 3 phase." @default.
• W3024256522 created "2020-05-21" @default.
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• W3024256522 date "2020-05-29" @default.
• W3024256522 modified "2023-09-27" @default.
• W3024256522 title "Effects of Sn Doping and A‐Site Deficiency on the Phases and Electrical Conductivities of the High‐Temperature Proton Conductor LaNbO ₄" @default.
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• W3024256522 doi "https://doi.org/10.1002/pssb.202000110" @default.
• W3024256522 hasPublicationYear "2020" @default.
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