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- W3024367780 abstract "A strategy for expanding the utility of chiral pyridine-2,6-bis(oxazoline) (pybox) ligands for asymmetric transition metal catalysis is introduced by adding a bidentate ligand to modulate the electronic properties and asymmetric induction. Specifically, a ruthenium(II) pybox fragment is combined with a cyclometalated N-heterocyclic carbene (NHC) ligand to generate catalysts for enantioselective transition metal nitrenoid chemistry, including ring contraction to chiral 2H-azirines (up to 97 % ee with 2000 TON) and enantioselective C(sp3)−H aminations (up to 97 % ee with 50 TON)." @default.
- W3024367780 created "2020-05-21" @default.
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- W3024367780 date "2020-06-05" @default.
- W3024367780 modified "2023-10-15" @default.
- W3024367780 title "Complementing Pyridine‐2,6‐bis(oxazoline) with Cyclometalated N‐Heterocyclic Carbene for Asymmetric Ruthenium Catalysis" @default.
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- W3024367780 doi "https://doi.org/10.1002/anie.202004243" @default.
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