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- W3024654768 abstract "We have prepared a new [Formula: see text]-oxo iron(III) porphyrin complex based on the simplest possible porphyrin ligand, porphine. Our structure determination for {[Fe(porphine)] 2 O}shows that it has a decidedly different molecular structure compared to all other [Formula: see text]-oxo iron(III)porphyrin complexes with two independent porphyrin ligands. The Fe–O–Fe angle is 153.21 (16)[Formula: see text]which leads to a small interplanar angle of 22.7[Formula: see text]between the two porphine rings. This also leads to C[Formula: see text]C nonbonded contact as short as 3.35Å between the two rings. The twist angle of the two porphine rings is 16.8[Formula: see text]. Other structural features are in general accord with those expected for high-spin iron(III) porphyrinates." @default.
- W3024654768 created "2020-05-21" @default.
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- W3024654768 date "2020-08-28" @default.
- W3024654768 modified "2023-09-26" @default.
- W3024654768 title "The Simplest Iron μ-oxo Species. The Molecular Structure of {[Fe(porphine)]<sub>2</sub>O}" @default.
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- W3024654768 doi "https://doi.org/10.1142/s108842462050025x" @default.
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