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- W3024865038 abstract "C–H Bond ActivationCatalytic borylation is the rare reaction that can selectively target stronger over weaker saturated carbon–hydrogen (C–H) bonds. However, the trade-off has been that the reaction is slow and requires high excess of the hydrocarbon. Oeschger et al. now report that the right ligand (2-methylphenanthroline) coordinated to iridium can accelerate the reaction by 50- to 80-fold. This rate enhancement enables selective borylation of primary C–H bonds with the hydrocarbon as limiting reagent. The reaction is also unusually selective for β-C–H bonds in saturated heterocycles.Science , this issue p. [736][1] [1]: /lookup/doi/10.1126/science.aba6146" @default.
- W3024865038 created "2020-05-21" @default.
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- W3024865038 date "2020-05-14" @default.
- W3024865038 modified "2023-10-18" @default.
- W3024865038 title "Speeding up borylation" @default.
- W3024865038 doi "https://doi.org/10.1126/science.368.6492.726-e" @default.
- W3024865038 hasPublicationYear "2020" @default.
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