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• W3025089077 startingPage "912" @default.
• W3025089077 abstract "Mechanically interlocked host frameworks are expected to show dynamic guest inclusion/release without disruption of their inherent structures. Here, we synthesized a double-walled knotted cage from a kinetically inert Pt(II) block, which has a robust but semiflexible backbone to give an expansible cavity with expansible portals. The Pt cage showed great kinetic stability toward base, acid, and nucleophiles. Comparisons of the kinetics with a Pd(II) analog strongly supported the portal expansion mechanism for the guest inclusion in the double-walled cages." @default.
• W3025089077 created "2020-05-21" @default.
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• W3025089077 date "2020-08-05" @default.
• W3025089077 modified "2023-10-03" @default.
• W3025089077 title "A Robust Double-walled Knotted Cage Revealed Guest Binding through Adaptive Portal Expansion" @default.
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• W3025089077 doi "https://doi.org/10.1246/cl.200282" @default.
• W3025089077 hasPublicationYear "2020" @default.
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