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- W3025106191 abstract "Electrochemical behaviour of triactivated thiopyrans has been investigated in protic medium. Electroreduction of 4-dimethylamino-2,3,5-trimethoxycarbonyl-4H-thiopyran I first led to 2,3, 5-trimethoxy-carbonyl-2H-thiopyran IV, with elimination of dimethylamine; further reduction at more negative potential gives equimolar mixture of 2,3,6-trimethoxycarbonyl-3,6-dihydro-2H-thiopyran V and 2,3, 6-trimethoxycarbonyl-5,6-dihydro-2H-thiopyran VI. The same mixture is obtained by reduction of either 4-dimethylamino-3,5,6-trimethoxycarbonyl-3,4-dihydro-2H-thiopyran II or 3,5,6-trimethoxycarbonyl-2H-thiopyran III. Intermediate formation of a delocalised carbanion is postulated in order to explain these results." @default.
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- W3025106191 date "1997-01-01" @default.
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- W3025106191 title "Electrochemical access to functionalized dihydrothiopyran derivatives—Part 2. Electroreduction of triactivated 4H-thiopyrans" @default.
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- W3025106191 doi "https://doi.org/10.1016/s0013-4686(97)85498-9" @default.
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