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• W3025308093 endingPage "18783" @default.
• W3025308093 startingPage "18776" @default.
• W3025308093 abstract "The relatively sluggish lithium ion diffusion of LiNi1/3Co1/3Mn1/3O2 (NCM) is one of the fatal factors which can significantly prevent its widespread usage in high-power applications. In this work, the monodispersed hierarchical porous yolk-shell-like LiNi1/3Co1/3Mn1/3O2 (YS-NCM) with exposure to {010} electrochemical active facets was successfully synthesized, aiming to elevate the lithium ion diffusion ability and thus to enhance the electrochemical performance. The hierarchical porous nano-/microsphere morphology as well as the voids between the yolk and the shell allow for shortened Li+ diffusion pathways, leading to improved Li+ diffusion capability. These voids are also beneficial for providing more buffers for the volume changes during repeated charge and discharge. Additionally, the exposure of {010} electrochemical active facets provides more open structure for unimpeded Li+ migration. Therefore, by this design strategy, the lithium ion transport kinetics is greatly improved, yielding superior electrochemical performances. When examined as the cathode material for lithium-ion batteries (LIBs), the YS-NCM-based cells have achieved superior rate capability and stable cycling performance, rendering it as a promising cathode candidate for practical lithium-ion battery applications." @default.
• W3025308093 created "2020-05-21" @default.
• W3025308093 creator A5001609027 @default.
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• W3025308093 date "2020-01-01" @default.
• W3025308093 modified "2023-10-16" @default.
• W3025308093 title "Hierarchical porous LiNi_1/3Co_1/3Mn_1/3O₂ with yolk–shell-like architecture as stable cathode material for lithium-ion batteries" @default.
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• W3025308093 doi "https://doi.org/10.1039/d0ra03022h" @default.
• W3025308093 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35518293" @default.
• W3025308093 hasPublicationYear "2020" @default.
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