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- W3025654008 abstract "Abstract New diorganopnicogen(III) compounds of type [CH3OCH2CH2N(CH2C6H4)2]ML (M = Sb, L = ONO2 (3), OSO2CF3 (4); M = Bi, L = ONO2 (5), OSO2CF3 (6), OSO2C6H4(CHCH2)-4 (7) based on a heterocyclic butterfly-like tetrahydro-dibenzo[c,f][1,5]azastibocine/azabismocine skeleton were prepared by ligand exchange reactions between [CH3OCH2CH2N(CH2C6H4)2]MX (M = Sb, X = Cl (1); M = Bi, X = Br (2) and the appropriate silver salt. The new compounds 1 and 3–7 were structurally characterized by NMR and IR spectroscopy. For compounds 5, 7‧CHCl3 and the hydrolysis product [{CH3OCH2CH2N(CH2C6H4)2}BiOH2][CF3SO3] (6h) the crystal and molecular structures were determined by single-crystal X-ray diffraction. Strong transannular N→Bi interactions accompanied by strong MeO→Bi intramolecular interactions result in hypercoordinated species: 14‒Bi‒6 in 5, with a unisobidentate ONO2 ligand, and 12‒Bi‒5 in the cation of 6h and in 7‧CHCl3, with a monodentate OSO2C6H4(CHCH2)-4 ligand. The molecules are associated in dimeric units by Bi⋯π arene interactions (approx. 3.50 A). Weak H⋯O (in 5), H⋯π arene (in 7‧CHCl3), H⋯π arene, H⋯O and H⋯F (in 6h) intermolecular interactions contribute to supramolecular networks in all three compounds." @default.
- W3025654008 created "2020-05-21" @default.
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- W3025654008 date "2020-08-01" @default.
- W3025654008 modified "2023-10-18" @default.
- W3025654008 title "Hypercoordinated diorganopnicogen(III) compounds based on a butterfly-like skeleton of type [CH3OCH2CH2N(CH2C6H4)2]M (M = Sb, Bi)" @default.
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- W3025654008 doi "https://doi.org/10.1016/j.jorganchem.2020.121343" @default.
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