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Matches in SemOpenAlex for { <https://semopenalex.org/work/W3025755469> ?p ?o ?g. }

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• W3025755469 abstract "The Taxol core was prepared in five steps via a key copper-catalyzed asymmetric conjugate addition trapping sequence. The use of a bromodiene-derived alkylzirconium nucleophile followed by trapping with POCl3/DMF gave a highly functionalized intermediate featuring a quaternary center in 69% yield with 92% ee. After 1,2-addition, Suzuki–Miyaura cross-coupling, allylic oxidation, and a type II intramolecular Diels–Alder reaction, the taxol core was obtained in 11% overall yield with 92% ee." @default.
• W3025755469 created "2020-05-21" @default.
• W3025755469 creator A5005894917 @default.
• W3025755469 creator A5039761799 @default.
• W3025755469 date "2020-05-12" @default.
• W3025755469 modified "2023-09-27" @default.
• W3025755469 title "Synthesis of the Taxol Core via Catalytic Asymmetric 1,4-Addition of an Alkylzirconium Nucleophile" @default.
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• W3025755469 doi "https://doi.org/10.1021/acs.orglett.0c01165" @default.
• W3025755469 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32396003" @default.
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