FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3025900342> ?p ?o ?g. }

• W3025900342 endingPage "7613" @default.
• W3025900342 startingPage "7603" @default.
• W3025900342 abstract "One-dimensional coordination polymers constructed with the 4d metallo-ligand [Mo(NCS)6]3– associated with NiII and CoII complexes are reported. The first series consists of anionic NCS-bridged [Mo-MII]− coordination polymers associated with a discrete paramagnetic complex or a diamagnetic CoIII complex acting as cations. The latter takes advantage of the coordination preference of the S-ligand for the soft 3d ions and has led to hetero-trimetallic [MoIIINiIICoIII] and mixed valence [MoIIICoIICoIII] compounds. A second series concerns neutral chains in which trinuclear [Mo M2II] units are bridged by an additional NCS anion. The soft character of the S atom was also the key to a rare example of a compound involving both high-spin and low-spin CoII centers associated with [Mo(NCS)6]. A [Mo–Ni] derivative obtained with [Mo(NCSe)6]3– has been considered in order to evaluate the effect of Se versus S on the exchange interaction. The spin distribution for selenocyanate metallo-ligand has been assessed by density functional theory calculations. The crystal structures for all compounds have been characterized, and their magnetic behaviors have been investigated. These ferrimagnetic systems are characterized by antiferromagnetic Mo-MII interactions in the range of −40 to −90 cm–1 (based on H = −JSaSb formalism) operative both with CoII and with NiII, thus demonstrating the potential of the MoIII–NCS combination for molecular systems in which exchange interactions play an important role." @default.
• W3025900342 created "2020-05-21" @default.
• W3025900342 creator A5001953195 @default.
• W3025900342 creator A5010577943 @default.
• W3025900342 creator A5078808044 @default.
• W3025900342 creator A5083533877 @default.
• W3025900342 creator A5089602067 @default.
• W3025900342 date "2020-05-15" @default.
• W3025900342 modified "2023-10-02" @default.
• W3025900342 title "Molybdenum(III) Thiocyanate- and Selenocyanate-Based One-Dimensional Heteronuclear Polymers: Coordination Affinity-Controlled Assemblage of Mixed Spin and Mixed Valence Derivatives with Ni(II) and Co(II/III)" @default.
• W3025900342 cites W1769608610 @default.
• W3025900342 cites W1966182479 @default.
• W3025900342 cites W1969209869 @default.
• W3025900342 cites W1969360633 @default.
• W3025900342 cites W1970858951 @default.
• W3025900342 cites W1974608653 @default.
• W3025900342 cites W1983194115 @default.
• W3025900342 cites W1985500594 @default.
• W3025900342 cites W1987925548 @default.
• W3025900342 cites W1997258277 @default.
• W3025900342 cites W1999846725 @default.
• W3025900342 cites W2000618854 @default.
• W3025900342 cites W2004218359 @default.
• W3025900342 cites W2005877813 @default.
• W3025900342 cites W2008738159 @default.
• W3025900342 cites W2010821314 @default.
• W3025900342 cites W2013985799 @default.
• W3025900342 cites W2023271753 @default.
• W3025900342 cites W2024175762 @default.
• W3025900342 cites W2026953592 @default.
• W3025900342 cites W2027284010 @default.
• W3025900342 cites W2029736668 @default.
• W3025900342 cites W2030870294 @default.
• W3025900342 cites W2042268243 @default.
• W3025900342 cites W2044490585 @default.
• W3025900342 cites W2054424863 @default.
• W3025900342 cites W2060892721 @default.
• W3025900342 cites W2061544255 @default.
• W3025900342 cites W2065078696 @default.
• W3025900342 cites W2065626737 @default.
• W3025900342 cites W2068617439 @default.
• W3025900342 cites W2073498733 @default.
• W3025900342 cites W2075407188 @default.
• W3025900342 cites W2077819588 @default.
• W3025900342 cites W2083548631 @default.
• W3025900342 cites W2086359479 @default.
• W3025900342 cites W2090143557 @default.
• W3025900342 cites W2099370459 @default.
• W3025900342 cites W2117867509 @default.
• W3025900342 cites W2137706739 @default.
• W3025900342 cites W2142122857 @default.
• W3025900342 cites W2142848888 @default.
• W3025900342 cites W2143803583 @default.
• W3025900342 cites W2143981217 @default.
• W3025900342 cites W2149565378 @default.
• W3025900342 cites W2151675857 @default.
• W3025900342 cites W2153446935 @default.
• W3025900342 cites W2156142140 @default.
• W3025900342 cites W2165528549 @default.
• W3025900342 cites W2169690753 @default.
• W3025900342 cites W2314022001 @default.
• W3025900342 cites W2314516917 @default.
• W3025900342 cites W2322694752 @default.
• W3025900342 cites W2323064953 @default.
• W3025900342 cites W2324978030 @default.
• W3025900342 cites W2341876120 @default.
• W3025900342 cites W2345562211 @default.
• W3025900342 cites W2379197268 @default.
• W3025900342 cites W2623350364 @default.
• W3025900342 cites W2769374241 @default.
• W3025900342 cites W2789591615 @default.
• W3025900342 cites W2792691264 @default.
• W3025900342 cites W2889358101 @default.
• W3025900342 cites W2890923219 @default.
• W3025900342 cites W2896454371 @default.
• W3025900342 cites W2911642670 @default.
• W3025900342 cites W2951165804 @default.
• W3025900342 cites W2952016234 @default.
• W3025900342 cites W4248052365 @default.
• W3025900342 cites W4250451065 @default.
• W3025900342 cites W790136311 @default.
• W3025900342 doi "https://doi.org/10.1021/acs.inorgchem.0c00459" @default.
• W3025900342 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32412746" @default.
• W3025900342 hasPublicationYear "2020" @default.
• W3025900342 type Work @default.
• W3025900342 sameAs 3025900342 @default.
• W3025900342 citedByCount "13" @default.
• W3025900342 countsByYear W30259003422020 @default.
• W3025900342 countsByYear W30259003422021 @default.
• W3025900342 countsByYear W30259003422022 @default.
• W3025900342 countsByYear W30259003422023 @default.
• W3025900342 crossrefType "journal-article" @default.
• W3025900342 hasAuthorship W3025900342A5001953195 @default.
• W3025900342 hasAuthorship W3025900342A5010577943 @default.
• W3025900342 hasAuthorship W3025900342A5078808044 @default.
• W3025900342 hasAuthorship W3025900342A5083533877 @default.
• W3025900342 hasAuthorship W3025900342A5089602067 @default.
• W3025900342 hasBestOaLocation W30259003422 @default.

• next