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- W3025910273 endingPage "9931" @default.
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- W3025910273 abstract "A method for the site-selective and diastereoselective conjugate addition of boron-stabilized allylic nucleophiles to α,β-unsaturated ketones is disclosed. Transformations involve easily prepared γ,γ-disubstituted allyldiboron reagents and proceed in the presence of a fluoride activator at 80 °C. Reactions proceed with a wide variety of enones and allyldiboron reagents efficiently to deliver ketone products that contain otherwise difficult-to-access vicinal β-tertiary and γ-quaternary carbon stereogenic centers and an alkenylboron moiety. The utility of the method is highlighted by several transformations, including cross-coupling and carbocyclizations." @default.
- W3025910273 created "2020-05-21" @default.
- W3025910273 creator A5014651341 @default.
- W3025910273 creator A5057740779 @default.
- W3025910273 date "2020-05-14" @default.
- W3025910273 modified "2023-10-18" @default.
- W3025910273 title "Synthesis of Quaternary Carbon Stereogenic Centers by Diastereoselective Conjugate Addition of Boron-Stabilized Allylic Nucleophiles to Enones" @default.
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- W3025910273 doi "https://doi.org/10.1021/jacs.0c03900" @default.
- W3025910273 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7289652" @default.
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- W3025910273 hasPublicationYear "2020" @default.
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