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• W3026007625 endingPage "100437" @default.
• W3026007625 startingPage "100437" @default.
• W3026007625 abstract "Water oxidation is traditionally performed over IrO2 and RuO2 owing to their high stability at low pH compared to molecular O2 evolution catalysts. The low stability of molecular complexes in acids limits their industrial exploitation as anodes in water-splitting devices, where high current densities and proton conductivity are required. Herein, an existing Co(1,10-phenanthroline)2 complex film is engineered to improve its pH-stability via extra OH substituents on the ligand, i.e. 1,10-phenanthroline-4,7-diol. This novel Co(1,10-phenanthroline-4,7-diol)2 complex film is active for water oxidation at low overpotentials and stable at low pH. Since the calculated water oxidation overpotentials of both complexes are similar, the difference in water oxidation activity is attributed to a smaller charge transfer resistance, which originates from a different anchoring style to the electrode via the OH groups of the ligand. This result is supported by electrochemical impedance measurements. The high pH-stability of the Co(1,10-phenanthroline-4,7-diol)2 film is computationally rationalized by a high crystal formation energy observed in DFT calculations. In summary, an acid-stable and active cobalt-based metal-organic film is reported that competes well with most reported earth-abundant catalysts for water oxidation under similar conditions." @default.
• W3026007625 created "2020-05-21" @default.
• W3026007625 creator A5012282123 @default.
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• W3026007625 date "2020-09-01" @default.
• W3026007625 modified "2023-09-23" @default.
• W3026007625 title "Engineering of a highly stable metal-organic Co-film for efficient electrocatalytic water oxidation in acidic media" @default.
• W3026007625 cites W1816450589 @default.
• W3026007625 cites W1966689737 @default.
• W3026007625 cites W1969739156 @default.
• W3026007625 cites W1970127494 @default.
• W3026007625 cites W1974896731 @default.
• W3026007625 cites W1976204697 @default.
• W3026007625 cites W1978526482 @default.
• W3026007625 cites W1980942699 @default.
• W3026007625 cites W1981368803 @default.
• W3026007625 cites W1982153238 @default.
• W3026007625 cites W1986829915 @default.
• W3026007625 cites W1988091937 @default.
• W3026007625 cites W1992258332 @default.
• W3026007625 cites W1999797546 @default.
• W3026007625 cites W2005234587 @default.
• W3026007625 cites W2007395042 @default.
• W3026007625 cites W2017265384 @default.
• W3026007625 cites W2020007931 @default.
• W3026007625 cites W2020754298 @default.
• W3026007625 cites W2027167470 @default.
• W3026007625 cites W2032100925 @default.
• W3026007625 cites W2033987606 @default.
• W3026007625 cites W2034311877 @default.
• W3026007625 cites W2042902605 @default.
• W3026007625 cites W2048042455 @default.
• W3026007625 cites W2049638592 @default.
• W3026007625 cites W2057181362 @default.
• W3026007625 cites W2057482749 @default.
• W3026007625 cites W2057833130 @default.
• W3026007625 cites W2058442882 @default.
• W3026007625 cites W2060745946 @default.
• W3026007625 cites W2067238339 @default.
• W3026007625 cites W2076376643 @default.
• W3026007625 cites W2076968595 @default.
• W3026007625 cites W2078097019 @default.
• W3026007625 cites W2082345487 @default.
• W3026007625 cites W2083222334 @default.
• W3026007625 cites W2095474273 @default.
• W3026007625 cites W2103442387 @default.
• W3026007625 cites W2118278487 @default.
• W3026007625 cites W2125191072 @default.
• W3026007625 cites W2132612804 @default.
• W3026007625 cites W2133406747 @default.
• W3026007625 cites W2137776484 @default.
• W3026007625 cites W2142570128 @default.
• W3026007625 cites W2146546128 @default.
• W3026007625 cites W2147709613 @default.
• W3026007625 cites W2150697053 @default.
• W3026007625 cites W2169655552 @default.
• W3026007625 cites W2170670288 @default.
• W3026007625 cites W2174939110 @default.
• W3026007625 cites W2252937322 @default.
• W3026007625 cites W2296980838 @default.
• W3026007625 cites W2315133715 @default.
• W3026007625 cites W2316802195 @default.
• W3026007625 cites W2319044418 @default.
• W3026007625 cites W2337261154 @default.
• W3026007625 cites W2404306872 @default.
• W3026007625 cites W2558877322 @default.
• W3026007625 cites W2558998316 @default.
• W3026007625 cites W2559769634 @default.
• W3026007625 cites W2572765927 @default.
• W3026007625 cites W2610840529 @default.
• W3026007625 cites W2621868363 @default.
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• W3026007625 cites W2804972102 @default.
• W3026007625 cites W2809999169 @default.
• W3026007625 cites W2894033777 @default.
• W3026007625 cites W2900036754 @default.
• W3026007625 cites W2990800672 @default.
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• W3026007625 doi "https://doi.org/10.1016/j.mtener.2020.100437" @default.
• W3026007625 hasPublicationYear "2020" @default.
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