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- W3026280052 abstract "Efficient and energy-saving separation of benzene isomers bearing a diverse range of functional groups is a great challenge due to their overlapping physicochemical properties. Here, we report the successfully use of a water-soluble pillar[5]arene (WP5) as a multifunctional material for the separation and detection of meta/ortho-substituted benzene isomers in water. A liquid-liquid extraction strategy was used for the separation of these benzene isomers based on their different affinity for WP5 in water. The selectivities for the meta over the ortho isomer for xylenes, chlorotoluene, and bromotoluene was 88.6 %, 88.3 %, and 95.0 % respectively, in one extraction cycle. Furthermore, a fluorescence indicator system based on WP5 and a fluorescent dye molecule (10-methylacridinium, D) was adopted and exhibited significant fluorescence and optical discrimination upon the addition of meta- compared to ortho-xylene, which implies that a simple turn-on detection can be performed prior to engaging in the separation process." @default.
- W3026280052 created "2020-05-29" @default.
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- W3026280052 date "2020-06-01" @default.
- W3026280052 modified "2023-09-28" @default.
- W3026280052 title "Separation and Detection of <i>meta</i> ‐ and <i>ortho</i> ‐Substituted Benzene Isomers by Using a Water‐Soluble Pillar[5]arene" @default.
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- W3026280052 doi "https://doi.org/10.1002/cplu.202000275" @default.
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