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- W3026341770 abstract "Perylene-fused, aggregation-free polycyclic aromatic hydrocarbons with partial zigzag periphery (ZY-01, ZY-02, and ZY-03) were synthesized. X-ray crystallographic analysis reveals that there is no intermolecular π–π stacking in any of the three molecules, and as a result, they show moderate-to-high photoluminescence quantum yield in both solution and in the solid state. They also display the characteristic absorption and emission spectra of perylene dyes. ZY-01 and ZY-02 with a nearly planar π-conjugated skeleton exhibit amplified spontaneous emission (ASE) when dispersed in polystyrene thin films. Solution-processed distributed feedback lasers have been fabricated using ZY-01 and ZY-02 as active gain materials, both showing narrow emission linewidth (<0.4 nm) at wavelengths around 515 and 570 nm, respectively. In contrast, ZY-03 did not show ASE and lasing, presumably due to its highly twisted backbone, which facilitates nonradiative internal conversion and intersystem crossing." @default.
- W3026341770 created "2020-05-29" @default.
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- W3026341770 date "2020-06-25" @default.
- W3026341770 modified "2023-10-15" @default.
- W3026341770 title "Perylene‐Fused, Aggregation‐Free Polycyclic Aromatic Hydrocarbons for Solution‐Processed Distributed Feedback Lasers" @default.
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- W3026341770 doi "https://doi.org/10.1002/anie.202004789" @default.
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- W3026341770 hasPublicationYear "2020" @default.
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