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• W3026463453 abstract "Incorporation of 3-deoxy-, 4-deoxy-, and 6-deoxy-analogues of d-glucose into glycogen was investigated in a reaction catalyzed with yeast UDPglucogen glucosyl transferase. It was found that hydroxyl groups at positions C-3, C-4 and C-6 in the glucosyl moiety of the UDPG molecule are not essential for preserving its substrate properties in this transglycosylic reaction. The kinetics of 3-deoxy-, 4-deoxy- and 6-deoxy-glucose incorporation into glycogen was compared with that of d-glucose and 2-deoxy-glucose. It was found that the affinity of the enzyme and the rate of hexose incorporation into glycogen decreases in following sequence: d-glucose, 2-deoxy-, 6-deoxy-, 4-deoxy- and 3-deoxyglucose. The deoxyglucosyl analogues of UDPG act as competitive inhibitors on the reaction of glycogen biosynthesis." @default.
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• W3026463453 date "1973-12-01" @default.
• W3026463453 modified "2023-10-08" @default.
• W3026463453 title "Transglycosylic Reactions of Nucleotides of Deoxy-Sugars. 3-Deoxy-d-glucose, 4-Deoxy-d-glucose and 6-Deoxy-d-glucose Incorporation into Glycogen" @default.
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• W3026463453 doi "https://doi.org/10.1111/j.1432-1033.1973.tb03185.x" @default.
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