Matches in SemOpenAlex for { <https://semopenalex.org/work/W3027463751> ?p ?o ?g. }
- W3027463751 endingPage "7569" @default.
- W3027463751 startingPage "7562" @default.
- W3027463751 abstract "This study investigated the structural transformation, guest distributions, and the extent of replacement in CH4 + C3H8–flue gas replacement occurring in sII hydrates via gas chromatography, NMR spectroscopy, and powder X-ray diffraction (PXRD). Simulated flue gas (CO2 (20%) + N2 (80%)) was injected into an sII CH4 (90%) + C3H8 (10%) hydrate for guest exchange. The extent of replacement occurring in CH4 + C3H8–flue gas replacement was much lower than that of CH4 + C3H8–CO2 replacement. Furthermore, 13C NMR spectra and PXRD patterns revealed that unlike CH4 + C3H8–CO2 replacement, CH4 + C3H8–flue gas replacement did not undergo any structural transformation during the replacement (i.e., iso-structural replacement in the sII hydrate). Rietveld refinement of PXRD patterns of gas hydrates after replacement using flue gas injection demonstrated that CO2 molecules occupied both the small (512) and large (51264) cages, whereas N2 molecules occupied only the small (512) cages. CO2 and N2 were not complementary but competitive in replacing CH4 in the small (512) cages, which contributed to the maintenance of the cage stability of the initial sII hydrate and thus, resulted in a lower extent of replacement. The experimental results obtained in this study provide valuable insights on the accurate replacement mechanism and cage-specific guest exchange behavior of sII hydrates using flue gas injection for energy recovery and CO2 sequestration." @default.
- W3027463751 created "2020-05-29" @default.
- W3027463751 creator A5019085471 @default.
- W3027463751 creator A5024380911 @default.
- W3027463751 creator A5051230612 @default.
- W3027463751 creator A5072825403 @default.
- W3027463751 date "2020-05-22" @default.
- W3027463751 modified "2023-10-13" @default.
- W3027463751 title "Influence of Competitive Inclusion of CO<sub>2</sub> and N<sub>2</sub> on sII Hydrate–Flue Gas Replacement for Energy Recovery and CO<sub>2</sub> Sequestration" @default.
- W3027463751 cites W1834624031 @default.
- W3027463751 cites W1965988406 @default.
- W3027463751 cites W1970154530 @default.
- W3027463751 cites W1978624313 @default.
- W3027463751 cites W1992591787 @default.
- W3027463751 cites W1996055625 @default.
- W3027463751 cites W2005980756 @default.
- W3027463751 cites W2008709293 @default.
- W3027463751 cites W2011647863 @default.
- W3027463751 cites W2014017357 @default.
- W3027463751 cites W2023613994 @default.
- W3027463751 cites W2025141224 @default.
- W3027463751 cites W2031589630 @default.
- W3027463751 cites W2033527176 @default.
- W3027463751 cites W2033792428 @default.
- W3027463751 cites W2035024978 @default.
- W3027463751 cites W2037206582 @default.
- W3027463751 cites W2045937196 @default.
- W3027463751 cites W2048312071 @default.
- W3027463751 cites W2054614174 @default.
- W3027463751 cites W2054671743 @default.
- W3027463751 cites W2062911110 @default.
- W3027463751 cites W2064350654 @default.
- W3027463751 cites W2071165546 @default.
- W3027463751 cites W2072934354 @default.
- W3027463751 cites W2078602209 @default.
- W3027463751 cites W2085519620 @default.
- W3027463751 cites W2086623306 @default.
- W3027463751 cites W2108675475 @default.
- W3027463751 cites W2112382733 @default.
- W3027463751 cites W2115831405 @default.
- W3027463751 cites W2123310579 @default.
- W3027463751 cites W2128851532 @default.
- W3027463751 cites W2131499768 @default.
- W3027463751 cites W2158813471 @default.
- W3027463751 cites W2167382751 @default.
- W3027463751 cites W2189662415 @default.
- W3027463751 cites W2195667809 @default.
- W3027463751 cites W2460872592 @default.
- W3027463751 cites W2518990619 @default.
- W3027463751 cites W2519672115 @default.
- W3027463751 cites W2548765767 @default.
- W3027463751 cites W2559328342 @default.
- W3027463751 cites W2576580381 @default.
- W3027463751 cites W2738113256 @default.
- W3027463751 cites W2749672065 @default.
- W3027463751 cites W2775813252 @default.
- W3027463751 cites W2789781801 @default.
- W3027463751 cites W2809701925 @default.
- W3027463751 cites W2884797456 @default.
- W3027463751 cites W2901644345 @default.
- W3027463751 cites W2910989516 @default.
- W3027463751 cites W2939967004 @default.
- W3027463751 cites W2951684143 @default.
- W3027463751 cites W2955453670 @default.
- W3027463751 cites W406942438 @default.
- W3027463751 cites W4236730362 @default.
- W3027463751 doi "https://doi.org/10.1021/acs.est.0c00583" @default.
- W3027463751 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32441519" @default.
- W3027463751 hasPublicationYear "2020" @default.
- W3027463751 type Work @default.
- W3027463751 sameAs 3027463751 @default.
- W3027463751 citedByCount "24" @default.
- W3027463751 countsByYear W30274637512021 @default.
- W3027463751 countsByYear W30274637512022 @default.
- W3027463751 countsByYear W30274637512023 @default.
- W3027463751 crossrefType "journal-article" @default.
- W3027463751 hasAuthorship W3027463751A5019085471 @default.
- W3027463751 hasAuthorship W3027463751A5024380911 @default.
- W3027463751 hasAuthorship W3027463751A5051230612 @default.
- W3027463751 hasAuthorship W3027463751A5072825403 @default.
- W3027463751 hasConcept C100402318 @default.
- W3027463751 hasConcept C167206829 @default.
- W3027463751 hasConcept C178790620 @default.
- W3027463751 hasConcept C185039092 @default.
- W3027463751 hasConcept C185592680 @default.
- W3027463751 hasConcept C2781060337 @default.
- W3027463751 hasConcept C8010536 @default.
- W3027463751 hasConceptScore W3027463751C100402318 @default.
- W3027463751 hasConceptScore W3027463751C167206829 @default.
- W3027463751 hasConceptScore W3027463751C178790620 @default.
- W3027463751 hasConceptScore W3027463751C185039092 @default.
- W3027463751 hasConceptScore W3027463751C185592680 @default.
- W3027463751 hasConceptScore W3027463751C2781060337 @default.
- W3027463751 hasConceptScore W3027463751C8010536 @default.
- W3027463751 hasFunder F4320322120 @default.
- W3027463751 hasIssue "12" @default.
- W3027463751 hasLocation W30274637511 @default.
- W3027463751 hasLocation W30274637512 @default.