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• W3027658093 endingPage "7665" @default.
• W3027658093 startingPage "7657" @default.
• W3027658093 abstract "We report the synthesis and characterization of C2-symmetrical lanthanide complexes supported by enantiopure hexadentate ligands derived from 1,2-diaminocyclohexane. Coordination of (R,R)- or (S,S)-N,N,N′,N′-tetrakis(2-pyridylmethyl)-trans-1,2-diaminocyclohexane (tpdac) to samarium, europium, terbium, and dysprosium generates the corresponding C2-symmetrical (tpdac)Ln(OTf)3 complexes in high yields. The tpdac ligands are competent sensitizers for lanthanide luminescence, yielding modest emissions (Φ of ≤28%). Additionally, the complexes exhibit strong circularly polarized luminescence (|glum| values of up to 0.13, 0.09, 0.22, and 0.15 for Sm, Eu, Tb, and Dy, respectively) in solution. We also observed that some transitions typically associated with small dissymmetry factors exhibit unusually high |glum| values and, therefore, should not be overlooked in future studies." @default.
• W3027658093 created "2020-05-29" @default.
• W3027658093 creator A5011489044 @default.
• W3027658093 creator A5041135027 @default.
• W3027658093 creator A5062063526 @default.
• W3027658093 date "2020-05-19" @default.
• W3027658093 modified "2023-09-28" @default.
• W3027658093 title "Circularly Polarized Luminescence from Enantiopure <i>C</i>₂-Symmetrical Tetrakis(2-pyridylmethyl)-1,2-diaminocyclohexane Lanthanide Complexes" @default.
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• W3027658093 doi "https://doi.org/10.1021/acs.inorgchem.0c00628" @default.
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• W3027658093 hasPublicationYear "2020" @default.
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