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- W3027856173 abstract "In the hexahedral hydrocarbon cubane, replacing hydrogen with other atoms at three positions within any one of the internal tetrahedrons can conceptually lead to the formation of a unique class of chiral molecules. In pursuit of this endeavor, we prepared 1,3-dibromo-4-deuteriocubane-N,N-diisopropylcarboxamide, which upon treatment with zincates affords 1,3,5-trisubstituted cubanes via simultaneous two-position substitution reactions. The proposed chiral attributes of this stereogeometric class were confirmed by enantiomeric resolution of a p-bromobenzyl derivative using chiral HPLC." @default.
- W3027856173 created "2020-05-29" @default.
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- W3027856173 date "2020-05-21" @default.
- W3027856173 modified "2023-10-18" @default.
- W3027856173 title "Cubane Chirality via Substitution of a “Hidden” Regular Tetrahedron" @default.
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- W3027856173 doi "https://doi.org/10.1021/acs.orglett.0c01142" @default.
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