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- W3027922988 abstract "In the present study, we report the synthesis of photoactive bismuth oxycarbonate (BOC, Bi2O2CO3) grafted NiFe layered double hydroxide (LDH) supported on g-C3N4 (15 wt% of g-C3N4) by coprecipitation method. The band gap of this photoactive material is determined to be 1.7 eV. The Bi2O2CO3 agglomerates are anchored on NiFe-LDH plates and g-C3N4 nanosheets intercalated between the LDH plates. This architecture helps in expediting electron transfer for hydrogen and oxygen evolution reactions. The pristine NiFe-LDH photoanode acquires bifunctional character because of Bi2O2CO3 agglomerates and g-C3N4 embedded in the architecture of BOC/[email protected]3N4. This is found to be an efficient photoanode for oxygen evolution and photocathode for hydrogen evolution reactions. The water splitting process occurs along the heterojunction formed between g-C3N4 nanosheets and Bi2O2CO3 grafted NiFe-LDH. Further, an additional interfacial charge transfer aided by Bi2O2CO3 results in S-scheme mechanism, which enhances the rate of photoelectrochemical hydrogen and oxygen evolution reactions." @default.
- W3027922988 created "2020-05-29" @default.
- W3027922988 creator A5077021258 @default.
- W3027922988 creator A5091201213 @default.
- W3027922988 date "2021-03-01" @default.
- W3027922988 modified "2023-09-25" @default.
- W3027922988 title "Bismuth oxycarbonate grafted NiFe-LDH supported on g-C3N4 as bifunctional catalyst for photoelectrochemical water splitting" @default.
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- W3027922988 doi "https://doi.org/10.1016/j.ijhydene.2020.04.116" @default.
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