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- W3028242135 abstract "We explore the consequences of nonthermal plasma-activation on product yields in catalytic ammonia synthesis, a reaction that is equilibrium-limited at elevated temperatures. We employ a minimal microkinetic model that incorporates the influence of plasma-activation on N2 dissociation rates to predict NH3 yields into and across the equilibrium-limited regime. NH3 yields are predicted to exceed bulk thermodynamic equilibrium limits on materials that are thermal-rate-limited by N2 dissociation. In all cases, yields revert to bulk equilibrium at temperatures at which thermal reaction rates exceed plasma-activated ones. Beyond-equilibrium NH3 yields are observed in a packed bed dielectric barrier discharge reactor and exhibit sensitivity to catalytic material choice in a way consistent with model predictions. The approach and results highlight the opportunity to exploit synergies between nonthermal plasmas and catalysts to affect transformations at conditions inaccessible through thermal routes." @default.
- W3028242135 created "2020-05-29" @default.
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- W3028242135 date "2020-05-18" @default.
- W3028242135 modified "2023-10-03" @default.
- W3028242135 title "Plasma-Catalytic Ammonia Synthesis beyond the Equilibrium Limit" @default.
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- W3028242135 doi "https://doi.org/10.1021/acscatal.0c00684" @default.
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